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Chemicals

Patents Available to License or Purchase

CHEMICALS

Our membranes are hermetic thereby preventing mixing of anolyte and catholyte solutions. They are also ion-selective allowing only Na+ or Li+ to go though. They have the requisite chemical compatibility with large set of chemicals. These features allows production of energetic and high-purity chemicals from low-cost, impure and industrial waste feedstocks. Finally, the membranes can be made in large area plate and tube formats and can be used as a replacement for polymer membranes in electrosynthesis applications.


The membranes can be applied for anodic decarboxylation of sodium carboxylates to produce radicals or carbocations that can then be converted into valuable low-oxygen organics.

Several chemicals including low/high carbon number linear/branched alkanes, alkenes, dienes, alcohols and diols can be produced by decarboxylation of carboxylate feedstocks using our membrane technology. This technology uses low-cost impure carboxylic acid feedstocks from biomass and convert them to industrial commodity chemicals such as surfactants, lubricants, monomers, high-energy fuels such as JP-8 and gasoline.

Radical Coupling to Make Dimers
High-Strength Patents

U.S. Patents: 4 issued, 6 applications
Non-U.S. patents: 5 issued, 20 applications

Patent No.: US 8,506,789 B2

STRENGTH
90%
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Method of producing coupled radical products.

Patent No.: US 8,853,463 B2

STRENGTH
81%
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Decarboxylation of levulinic acid to ketone solvents.

Patent No.: US 9,051,656 B2

STRENGTH
73%
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Electrochemical synthesis of aryl-alkyl surfactant precursor.

The present solid-electrolyte membranes can be used to make high purity, low-moisture containing sodium and lithium alcoholates in a simple two-compartment electrolysis cell.

We have made pilot-scale demonstration of producing sodium methylate (methoxide) that is the catalyst in the transesterification of triglycerides to biodiesel. The patented process converts aqueous sodium hydroxide to sodium methylate in methanol in an electrolysis reactor containing sodium conducting membrane. Other reagent grade lithium and sodium alcoholates can be similarly produced.

Alcoholates (Methylaye, Ethylate, Etc.)
High-Strength Patents

U.S. Patents: 2 issued
Non-U.S. patents: 2 issued, 1 application

Patent No.: US 7,918,986 B2

STRENGTH
89%
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Title: Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes.

Patent No.: US 7,959,784 B2

STRENGTH
87%
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Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes.

Patent No.: US 7,824,536 B2

STRENGTH
84%
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Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes.

Another group of applications for our membranes is in recovering or producing valuable inorganic sodium and lithium chemicals from low-cost & impure aqueous feedstocks.

The membrane technology can be applied for two- & three- compartment electrochemical salt splitting by which an impure sodium and lithium salts can be converted to purer and higher value salts, bases and acids. Examples of the processes include production of sodium hypochlorite (bleach) from sodium chloride brine, baking soda from caustic, and lactic acid from sodium lactate. Lithium and sodium in concentrated form can be recovered from industrial streams containing low-concentrations of these alkali metal ions.

Production and Utilization of Chemicals Containing Sodium
High-Strength Patents

U.S. Patents: 1 issued, 2 applications
Non-U.S. patents: 1 issued, 3 applications

Patent No.: US 8,268,159

STRENGTH
92%
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Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes.

Patent No.: US 9,611,555 B2

STRENGTH
70%
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Chemical systems and methods for operating an electrochemical cell with an acidic anolyte.

Patent No.: US 9,057,137 B2

STRENGTH
68%
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Method and device for carboxylic acid production.


PATENTS FOR ORGANIC ELECTROSYNTHESIS

Decarboxylation

Patent Strength & Vision Per Company, Organic Electrosynthesis

PATENTS FOR SODIUM AND LITHIUM CHEMICALS

Sodium Chemicals by Membrane Electrolysis

Patent Strength & Vision Per Company, Sodium and Lithium Chemicals

 Click Charts to Enlarge

The Vision and Patent strength values are obtained from Innography® IP intelligence software.

 

What can we do for you?

Together with our material scientists, chemical and mechanical engineers, and electrochemists, we can help you solve problems and unleash the potential of technologies in the commercial marketplace.

Phone: 801-972-2455
Email: info@ceramatec.com